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Nitrogen

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Preparation of Nitrogen(Laboratory Method):

NH4Cl + NaNO2 NaCl + N2 + H2O

         

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Preparation of Nitrogen(Other methods):

1.When orange Ammonium dichromate is heated, green Chromium oxide and Nitrogen gas are formed:

(NH4)2Cr2O7 Cr2O3 N2 + H2O

         

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2.When Ammonia gas is passed over heated black Copper(II) oxide, brown Copper powder, water and Nitrogen gas are formed:

NH3 + CuO → Cu + H2O + N2

         

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3.When Ammonia gas is passed over heated yellow Lead(II) oxide, grey Lead powder, water and Nitrogen gas are formed:

NH3 + PbO → Pb + H2O + N2

         

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Reactions of Nitrogen:

1.At 3000oC or during lightning discharge Nitrogen reacts with Oxygen to form Nirogen monoxide(Nitric oxide):

N2 + O2NO

         

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2.When A mixture of Nitrogen gas and Hydrogen gas is passed over Iron catalyst at 200 atm pressure and 450oC, Ammonia gas is formed:

N2 + H2  ⇌   NH3

        

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3. Burning Calcium metal reacts with Nitrogen to form Calcium nitride:

Ca + N2Ca3N2

         

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4. Burning Magnesium metal reacts with Nitrogen to form Magnesium nitride:

Mg + N2Mg3N2

         

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5. Red hot Aluminium metal reacts with Nitrogen to form Aluminium nitride:

Al + N2AlN

         

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6.At 1000oC Calcium carbide reacts with Nitrogen to form the fertilizer Nitrolim(A mixture of Calcium cyanamide and Carbon):

CaC2 + N2CaCN2 + C

         

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